Structural determination of N-2′-hydroxyoctadecenoyl-1-O-β-d-glucopyranosyl-9-methyl-4, 8-sphingadienine from species of Aspergillus

MHSV Boas, H Egge, G Pohlentz, R Hartmann… - Chemistry and physics …, 1994 - Elsevier
Ceramide monohexosides from Aspergillus fumigatus 2140 and 2109 strains and
Aspergillus versicolor 550 strain, obtained by silica gel 60, and Iatrobeads chromatography
were analysed using high-resolution 1D-, 2D-1 H-NMR and 13 C-NMR spectroscopy and
fast atom bombardment mass spectrometry (FAB-MS). The ceramide monohexoside fraction
(CMH) from A. fumigatus 2140 and A. versicolor 550 was identified as glucosylceramide,
whereas glucose and galactose were present at a ratio of 1: 1 in the CMH of A. fumigatus …